People have been talking about doing Laser-induced breakdown spectroscopy in space for decades, so I hope it works well with Chemcam. It has a lot of promise, both to speed up exploration, and in places like asteroids and comets, where it may not be feasible or safe to actually touch the target.
They have picked a boring nearby rock for the first target. There has been a discussion of whether or not Mars rocks have a "desert patina" (or varnish), and, if so, what is its nature, and even if it has a biological component. The Chemcam samples the top layer of the target, so may help to answer that.
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